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Amphiphilic complexes with luminescent rare earth metal ions suitable for Lanmuir-Blodgett (LB) deposition have been synthesized. LB monolayers with closely packed Eu complexes deposited directly on silver demonstrate significant far-field emission in contrast to the theoretical predictions of full quenching. Angular radiation and polarization patterns of the electric and magnetic dipole emission of Eu³⁺point to a high excitation efficiency of surface plasmon polaritons. Different luminescent behavior of closely packed emitters in comparison to diluted systems is tentatively attributed to the collective state of emitters in LB layers formed via near-field coupling with surface plasmons.

 

Abstract We have studied effects of metal–dielectric substrates on photopolymerization of [2,2ʹ-Bi-1H-indene]-1,1ʹ-dione-3,3ʹ-diyl diheptanoate (BITh) monomer. We synthetized BITh and spin-coated it onto a variety of dielectric, metallic, and metal–dielectric substrates. The films were exposed to radiation of a UV–Visible Xe lamp, causing photo-polymerization of monomer molecules. The magnitude and the rate of the photo-polymerization were monitored by measuring the strength of the ~ 480 nm absorption band, which existed in the monomer but not in the polymer. Expectedly, the rate of photo-polymerization changed nearly linearly with the change of the pumping intensity. In contrast with our early study of photo-degradation of semiconducting polymer P3HT, the rate of photo-polymerization of BITh is getting modestly higher if the monomer film is deposited on top of silver separated from the monomer by a thin insulating MgF 2 layer preventing a charge transfer. This effect is partly due to a constructive interference of the incident and reflected light waves, as well as known in the literature effects of metal/dielectric substrates on a variety of spectroscopic and energy transfer parameters. At the same time, the rate of photopolymerization is getting threefold larger if monomer is deposited on Ag film directly and charge transfer is allowed. Finally, Au substrates cause modest (~ 50%) enhancement of both monomer film absorption and the rate of photo-polymerization. 

Permalloy films with one-dimensional profile modulation of submicron periodicity are fabricated based on commercially available DVD-R discs and studied using ferromagnetic resonance method and micromagnetic numerical simulations. The main resonance position shows in-plane angular dependence which is strongly reminiscent of that in ferromagnetic films with uniaxial magnetic anisotropy. The main signal and additional low-field lines are attributed to multiple standing spin-wave resonances defined by the grating period. The results may present interest in magnetic metamaterials and magnonics applications. 

Plasmon-induced photocurrents in 1D profile modulated structures switch their polarity in the presence of an additional monolayer at the metal-dielectric interface. The effect presents opportunities for compact plasmonic sensors with electrical detection 

The generation of significant photocurrents observed in plasmonic metasurfaces is interesting from a fundamental point of view and promising for applications in plasmon-based electronics and plasmonic sensors with compact electrical detection. We show that photoinduced voltages in strongly modulated plasmonic surfaces demonstrate a highly asymmetric angular dependence with polarity switching around the plasmon resonance conditions. The effects are tentatively attributed to coupling between localized and propagating plasmons.

 

We have studied optical properties of single and multi-fold nanoporous gold leaf metamaterials and demonstrated that they can be controlled with applied voltage and dielectric environment. 

Profile-modulated permalloy films are promising for magneto-optical applications. We show that such systems demonstrate plasmonic properties and have uniaxial in-plane anisotropy, which may allow sharp magnetization switching using SAM of light.